Unit 6 – Energy Resources and Consumption

AP Environmental Science (APES)

16-17 Class Periods
10-15% AP Exam Weighting

6.1 Renewable and Nonrenewable Resources

Fundamental Definitions

Energy resources are classified based on their renewability - whether they can be replenished within human timescales or are finite.

Renewable Resources

Definition: Energy sources that are naturally replenished on human timescales (years to decades); sustainable if used at regeneration rate or less.

  • Solar Energy: Sunlight intercepted and converted to electricity/heat; inexhaustible on human timescale (5+ billion years remaining)
  • Wind Energy: Wind turbines capture kinetic energy; powered by solar heating and Coriolis effect
  • Hydroelectric: Flowing/falling water turns turbines; perpetual water cycle replenishes supply
  • Geothermal: Earth's internal heat; effectively inexhaustible on human timescales
  • Biomass: Organic material from plants/animals; renewable if harvested sustainably (regrowth replenishes)
  • Key Advantage: Don't deplete resource base; can be used indefinitely if managed sustainably

Nonrenewable Resources

Definition: Energy sources from finite stores formed over geological timescales (millions of years); depleted faster than they form.

  • Fossil Fuels: Coal, oil, natural gas formed from ancient organic matter over millions of years; cannot be replenished on human timescale
  • Nuclear: Uranium and thorium depleted with use; new deposits found slowly
  • Known Reserves: Coal ~100+ years, Oil ~50 years, Natural Gas ~50 years (at current consumption rates)
  • Key Challenge: Eventually deplete; must develop alternatives before running out
  • Environmental Impact: Extraction damages ecosystems; combustion releases CO₂ and pollutants

Global Energy Context

  • Current Reality: ~80% of global energy from fossil fuels; only ~20% from renewables (though increasing rapidly)
  • Renewable Growth: Solar and wind fastest-growing energy sources; doubling every 5-7 years; cost decreasing 90% since 2010
  • Energy Security: Transitioning to renewables improves energy independence; reduces geopolitical conflicts over oil/gas
  • Climate Imperative: Must transition to renewables to limit climate change; fossil fuels incompatible with climate goals
  • Development: Renewable energy enables energy access in remote areas without grid infrastructure

⚠️ Common Pitfall: Don't assume all renewables are unlimited! Renewable means naturally replenished, NOT infinite capacity. Solar/wind vary with weather. Hydroelectric depends on precipitation. Biomass can be over-harvested. Geothermal has location limits. Sustainable use of renewables still required. Know percentage of global energy from each source!

6.2 Global Energy Consumption

Overview and Scale

Global energy consumption continues rising rapidly, driven by population growth, industrialization, and increasing per-capita demand. Understanding consumption patterns is essential for predicting future energy needs and environmental impacts.

Key Statistics (Global Energy, 2024)

  • Total Energy: ~600 exajoules (EJ) annually; growing ~2% per year
  • Energy Source Breakdown: Oil ~30%, Coal ~25%, Natural Gas ~25%, Nuclear ~4%, Renewables ~16% (hydro ~6%, solar/wind ~12%, biomass ~4%, geothermal ~1%)
  • Fossil Fuels Dominance: ~80% of energy still from coal, oil, gas; despite renewable growth, absolute use of fossil fuels increasing (not decreasing)
  • Regional Variation: Developed nations: diverse mix (some 80%+ nuclear+renewables); developing nations: coal-dependent; China = world's largest coal consumer
  • Per-Capita: USA ~300 GJ/person/year; Global average ~80 GJ/person/year; huge disparity (wealthy use 10x more)

End-Use Energy (How We Use It)

  • Transportation: ~27% of energy (heavily oil-dependent; cars/planes/ships); difficult to transition away from fossil fuels
  • Industry: ~32% of energy (steel, cement, chemicals production; energy-intensive processes)
  • Residential/Commercial: ~30% of energy (heating, cooling, appliances, lighting); easier to transition to renewables
  • Agriculture: ~11% of energy (machinery, fertilizer, irrigation; often overlooked)
  • Key Challenge: Transportation and industry hardest to decarbonize; need breakthrough technologies

Trends and Projections

  • Continued Growth: Energy demand projected to increase 50% by 2050 (developing nations industrializing; air conditioning/electrification expanding)
  • Renewable Growth: Solar and wind capacity expanding rapidly; costs falling; becoming cheapest electricity source in many regions
  • Electrification: Transition from combustion engines to electric vehicles; heating to heat pumps; requires massive electricity generation increase
  • Grid Challenge: Renewable intermittency requires energy storage solutions (batteries, hydrogen, pumped hydro)
  • Net-Zero Path: Requires 50%+ emissions reduction by 2030; only possible with massive renewable deployment + efficiency improvements

Energy Efficiency and Conservation

  • Low-Hanging Fruit: 20-30% energy savings possible with current technology through efficiency improvements
  • Examples: Building insulation, LED lighting, efficient motors, heat recovery; often pay for themselves within years
  • Importance: Efficiency reduces demand; means less generation needed; cheapest "energy" is energy not used
  • Rebound Effect: Some efficiency gains offset by increased consumption (energy cheaper = use more); prevents 100% efficiency savings

6.3 Fuel Types and Uses

Classification by Primary Use

Different fuels have specific applications based on energy density, combustion properties, and infrastructure. Understanding fuel types and their uses is essential for energy planning.

Transportation Fuels

  • Petroleum/Gasoline: Most common; high energy density; infrastructure well-developed; cars, trucks, planes, ships
  • Diesel: Higher energy density than gasoline; more efficient; trucks, ships, trains; more pollution
  • Biofuels (Ethanol, Biodiesel): Plant-based; reduces fossil fuel dependence; but competes with food production; net carbon benefit debated
  • Electricity: Growing for EVs; increasingly renewable; requires massive battery manufacturing
  • Hydrogen: Emerging fuel for heavy transport; zero emissions (if produced from renewables); infrastructure lacking
  • Jet Fuel: Specialized for aviation; energy-dense; no viable renewable alternative yet (sustainable aviation fuels developing)

Electricity Generation Fuels

  • Coal: Thermal plants burn coal to heat water, create steam, turn turbines; ~40% efficient; emissions intensive
  • Natural Gas: Burns in combustion turbines; ~50-60% efficient (especially combined-cycle); lower emissions than coal but still fossil fuel
  • Nuclear: Fission heats water to steam; ~90% efficient; no CO₂ but radioactive waste concern; difficult to build
  • Hydroelectric: Water flow/height turns turbines; ~85% efficient; variable with precipitation
  • Solar (PV): Semiconductor converts photons to electrons; ~15-25% efficient; modular, scalable
  • Wind: Turbines capture kinetic energy; ~35-45% efficient; variable with wind speed
  • Geothermal: Steam from Earth drives turbines; ~10% of potential utilized; location-limited
  • Biomass: Burn plant material for electricity; carbon-neutral if sustainably harvested

Heating/Cooling Fuels

  • Natural Gas: Most common for home heating; efficient; requires pipeline infrastructure
  • Oil: Heating oil for furnaces; common in cold regions; expensive; being phased out
  • Electricity: Heat pumps (increasingly popular); resistance heating; requires efficient grid
  • Biomass: Wood, pellets, agricultural waste; renewable; pollution concerns if not clean-burning
  • Solar Thermal: Direct sun heat for water/space heating; ~70-80% efficient; limited to sunny regions
  • District Heating: Central plant distributes hot water; efficient for dense urban areas

Energy Density Comparison

MJ/kg (megajoules per kilogram): Gasoline ~46, Diesel ~45, Natural Gas ~55, Coal ~24, Wood ~15, Uranium ~80 million (nuclear). Higher density = more energy per unit mass/volume = better for transportation/portability.

6.4 Distribution of Natural Energy Resources

Overview and Geopolitical Implications

Energy resources are unevenly distributed globally, creating profound geopolitical, economic, and security implications. Countries with resources gain power; countries dependent on imports face vulnerability. Renewable transition promises to redistribute energy power by providing resources more widely available.

Fossil Fuel Distribution

Oil (Petroleum) Distribution

  • Top Producers: USA (~13 million barrels/day), Saudi Arabia (~10), Russia (~10), Canada (~5), Iraq (~4)
  • Proven Reserves: Saudi Arabia (268 Gb - gigabarrels), Russia (106), USA (53), Libya (48), Iran (156 - disputed)
  • Middle East Dominance: 48% of world reserves; OPEC cartel (Saudi Arabia, Iraq, Iran, UAE, Kuwait, Libya, etc.) controls ~30% of production
  • Geopolitical Power: Oil-rich nations leverage resource for political/military power (Saudi Arabia, Russia, Venezuela, Iran); oil price shocks destabilize economies
  • Reserve Debates: Proven reserves are economically extractable at current prices; as prices rise, unconventional oil (tar sands, shale, deep-water) becomes viable; "peak oil" concept suggests future production declines
  • Unconventional Oil: Tar sands (Canada), shale (USA), deep-water (Brazil, Gulf Mexico); environmentally damaging; more expensive; required as conventional depletes
  • Strategic Reserves: Countries maintain emergency supplies; USA Strategic Petroleum Reserve can offset supply disruptions

Natural Gas Distribution

  • Top Producers: USA (~900 billion cubic meters/year), Russia (~700), Iran (~240), Qatar (~180), Australia (~130)
  • Proven Reserves: Russia (37% of world reserves), Iran (18%), Qatar (13%), USA (8%), Turkmenistan (4%)
  • Infrastructure Dependent: Unlike oil (easy to ship), natural gas requires pipelines or liquefied natural gas (LNG) terminals; expensive infrastructure creates dependency
  • Geopolitical Leverage: Russia uses gas supplies to pressure Europe (Nord Stream pipelines, cutoffs); Ukraine crisis demonstrated vulnerability
  • LNG Trade: Qatar, Australia, USA export LNG globally; enables diversification away from pipeline dependence; more expensive than piped gas
  • Shale Gas Revolution: USA shale fracking transformed it from importer to exporter; made US more energy independent; environmental concerns (water, earthquakes)
  • Stranded Gas: Reserves in remote areas lack infrastructure to reach markets; economically unviable without major investment

Coal Distribution

  • Top Producers: China (~3,600 million tonnes/year, ~50% global), India (~700), USA (~600), Indonesia (~600), Australia (~500)
  • Proven Reserves: USA (268 billion tonnes), Russia (160), China (143), India (92), Australia (75)
  • Advantages vs. Oil/Gas: Widely distributed; most countries have coal reserves; less geopolitical concentration; easier to transport (ship, rail)
  • Global Spread: Coal production in 50+ countries; no single nation dominance like oil/gas; reduces leverage for supply cutoffs
  • Abundance: Coal reserves ~100+ years at current consumption; longest supply duration of fossil fuels
  • China's Dominance: Produces, consumes, and exports coal; fueling rapid industrialization; coal-dependent economy resists climate action
  • Mining Locations: Surface mines in USA, Australia, Indonesia; underground mines in China, India; environmental disruption varies

Uranium Distribution

  • Top Producers: Kazakhstan (~43% of world supply), Canada (~12%), Namibia (~8%), Australia (~8%), Uzbekistan (~7%)
  • Proven Reserves: Australia, Kazakhstan, Canada; relatively concentrated; geopolitical leverage for nuclear expansion
  • Price Volatility: Uranium prices vary ~100% over decades; exploration activity follows price cycles; long lead times (10+ years) to develop mines
  • Supply Security: Countries pursuing nuclear consider uranium security important; long-term contracts common; strategic reserves established
  • Enrichment Concentration: Uranium enrichment (weapons-grade vs. reactor-grade) concentrated in Russia, France, USA; key geopolitical chokepoint
  • Supply Duration: Current reserves ~90 years at today's consumption; 300+ years with breeder reactors (not widely used)

Renewable Energy Distribution

Solar Energy Distribution

  • Solar Intensity: Greatest near equator (consistent year-round); decreases toward poles (seasonal variation increases)
  • Best Regions: Desert/semi-arid zones (low cloud cover): Southwestern USA, Middle East, North Africa, Australia, India, Chile
  • Geographic Advantage: Solar available everywhere (even cloudy regions get some generation); enables energy independence in isolated areas without grid
  • Rural Electrification: Solar enables power in developing nations without centralized grid (Africa, India, Southeast Asia benefit)
  • No Geopolitical Concentration: Unlike oil/gas, solar power decentralized; reduces energy wars; improves energy security
  • Manufacturing Concentration: Solar panel manufacturing concentrated in China (~80% global production); creates supply chain dependency

Wind Energy Distribution

  • Wind Patterns: Strongest in coastal regions, mountains, plains; consistent in certain bands (trade wind zones, westerlies)
  • Best Regions: Northern Europe (Denmark, Germany, UK, Ireland), coastal USA, Patagonia, Inner Mongolia, Australia
  • Offshore Advantage: Ocean winds more consistent/stronger; Northern Europe pioneering offshore; China expanding offshore
  • Land Availability: Wind farms require large areas; compete for land with agriculture; can coexist (farmers lease land)
  • Fairly Distributed: Most regions have viable wind areas; enables diverse energy production across nations
  • Manufacturing: Turbine production more distributed than solar; USA, Europe, China, India major producers

Hydroelectric Distribution

  • Requirements: Requires high precipitation, elevation change, year-round water flow; mountains and well-watered regions only
  • Top Countries: Canada, Brazil, Norway, Russia, China - all have abundant water + mountains/elevation
  • Climate Dependency: Hydropower vulnerable to drought; variable with precipitation patterns; climate change creates uncertainty
  • Best Sites Developed: ~40% of economically viable hydropower already built; future expansion limited to remote/pristine areas (environmental conflicts)
  • Regional Concentration: Some nations hugely hydro-dependent: Norway (95%), Iceland (85%), Canada (60%); vulnerable to droughts
  • Equatorial Challenges: Tropical regions have rain but limited elevation; fewer large hydro opportunities

Geothermal Distribution

  • Tectonically Limited: Only economically viable in geothermally active regions along plate boundaries and hotspots
  • Top Countries: Iceland (30% of electricity), New Zealand, Philippines, Indonesia, Mexico, USA (California)
  • Ring of Fire: Pacific Rim most active; concentrated geothermal resources around Pacific Basin
  • Most Limited Distribution: Geothermal least widely available; cannot expand beyond tectonic activity; not solution for most nations
  • Enhanced Systems: EGS technology might expand viable areas; not yet commercial; high risk/cost
  • Direct Use Advantage: Countries with geothermal use for heating (Iceland, New Zealand); saves electricity/fossil fuels

Biomass Distribution

  • Widely Available: All regions produce biomass (forest, agricultural, animal waste); potential globally distributed
  • Abundant in Tropics: Highest biomass productivity in tropical regions (year-round growth); Africa, Southeast Asia, Central/South America potential
  • Industrial Countries: Scandinavian countries (forestry waste), USA (agricultural residue), Brazil (sugar bagasse)
  • Waste Potential: Every nation produces agricultural/forestry/animal waste; available for energy if collection systems established
  • Competition with Food: Biofuel crops compete with food production; land use conflict between energy and agriculture
  • Sustainability Variable: Depends on harvesting rates vs. regeneration; logging can exceed growth rates; unsustainable practice common

💡 Exam Tip: Fossil fuels concentrated in specific regions (Middle East oil, Russia gas); creates geopolitical leverage. Renewables more widely distributed; enables energy independence. Hydro needs mountains + water; geothermal limited to tectonics; solar/wind available everywhere (though variable). Know which countries produce/control key resources. Renewable transition redistributes energy power. Coal most widely distributed of fossils. OPEC controls 30% oil production.

6.5 Fossil Fuels

Formation and Characteristics

Formation: Accumulated organic matter from ancient plants/animals, buried under sediments, compressed over millions of years, heated by Earth's geothermal gradient. Processes take 50-300 million years; nonrenewable on human timescale.

Coal Formation and Types

  • Formation: Ancient plants (ferns, trees) in swamps; accumulated, buried, pressure/temperature converted to coal
  • Coal Ranks (by carbon content/energy):
  • 1. Lignite (40-50% carbon) = lowest rank, lowest energy, brown, crumbly, high ash
  • 2. Subbituminous (50-70% carbon) = intermediate, common in USA
  • 3. Bituminous (70-90% carbon) = most common, good quality, black
  • 4. Anthracite (90%+ carbon) = highest quality, rare, hot-burning
  • Characteristics: Solid, easy to mine and transport; energy density 20-24 MJ/kg; abundant reserves (~100+ years)
  • Uses: 70% electricity generation, steel production, heating, chemicals
  • Disadvantages: Dirtiest fossil fuel (most CO₂ per unit energy), massive air pollution (SO₂, NOx, particulates), mining damages ecosystems, ash disposal problem

Oil (Petroleum) Formation and Characteristics

  • Formation: Marine organisms (plankton, algae) accumulated in anaerobic (oxygen-free) conditions; buried 1-4 km; heated to 50-150°C; transformed to crude oil over 50-100 million years
  • Petroleum Composition: Mixture of hydrocarbons (alkanes, aromatics); carbon-hydrogen ratio ~85% C, 12% H, 3% other elements
  • Crude Oil Types: Light/sweet (low sulfur, easy refining) vs. Heavy/sour (high sulfur, viscous, more difficult)
  • Energy Density: 45-46 MJ/kg (higher than coal); liquid form convenient; easily transported
  • Products (Refining): Gasoline (transportation), diesel, jet fuel, heating oil, lubricants, petrochemicals (plastics, fertilizers, pharmaceuticals)
  • Uses: ~90% transportation, rest electricity/heating; globally ~100 million barrels/day
  • Extraction: Drilling wells (onshore/offshore); enhanced recovery using pressure/heat; deep-water and Arctic drilling expanding
  • Disadvantages: CO₂ emissions, air pollution, oil spills, pipeline leaks, habitat disruption, water contamination, geopolitical conflicts

Natural Gas Formation and Characteristics

  • Formation: Similar to oil; marine organisms in anoxic conditions; buried deeper/longer heating produces gas instead of liquid oil
  • Composition: Primarily methane (CH₄, 70-90%); ethane, propane, nitrogen, carbon dioxide; often found with oil deposits
  • Energy Density: 55 MJ/kg (highest of fossil fuels per unit mass); ~38 MJ/cubic meter (low density gas)
  • Uses: Heating (40%), electricity generation (30%), industrial processes (20%), transportation (3%), chemicals
  • Extraction: Drilling (conventional or unconventional shale/tight gas); liquefied natural gas (LNG) for transportation
  • Advantages vs. Coal/Oil: Cleanest burning (lowest CO₂ per unit energy, minimal air pollution); efficient (can be used in high-efficiency combined cycle plants)
  • Disadvantages: Methane leaks during production/transport (potent greenhouse gas); extraction impacts (water, earthquakes); fossil fuel nonetheless; lock-in infrastructure costs
  • Shale Gas/Fracking: Hydraulic fracturing enables extraction from low-permeability rock; expanded reserves dramatically; environmental concerns (water contamination, induced earthquakes, induced seismicity)

Environmental Impact of Fossil Fuels

Climate Change

  • CO₂ Emissions: Combustion oxidizes carbon to CO₂; coal most CO₂/energy (100+ g/MJ), oil moderate (75 g/MJ), gas cleanest (55 g/MJ)
  • Global Emissions: Fossil fuels responsible for ~75% of anthropogenic GHG emissions; CO₂ rising ~2% annually
  • Atmospheric Burden: CO₂ stays 200-1000 years; already committed to warming for centuries
  • Warming Trajectory: Current emissions path leads to 3-4°C warming by 2100; limit to 1.5-2°C requires rapid transition away from fossil fuels

Air Pollution

  • Particulate Matter: Coal burning produces soot, ash; fine particles (PM2.5) penetrate lungs; cardiovascular/respiratory disease
  • Sulfur Dioxide (SO₂): Coal contains sulfur; burning releases SO₂; causes acid rain (pH <5.6); damages forests, lakes, ecosystems; respiratory irritation
  • Nitrogen Oxides (NOx): High combustion temperatures form NOx; contributes to smog, acid rain; respiratory problems
  • Mercury and Heavy Metals: Coal contains mercury, arsenic, lead; emitted in smoke; bioaccumulates; neurotoxic to humans
  • Health Costs: WHO estimates 7+ million premature deaths annually from air pollution; most from fossil fuel combustion
  • Disproportionate Impacts: Indoor air pollution from coal heating kills millions in developing nations; outdoor pollution worst in Asia

Extraction and Production Impacts

  • Coal Mining: Surface mines destroy habitats, create dust pollution; acid mine drainage contaminates water for decades; worker health risks (black lung disease)
  • Oil Extraction: Drilling damages ecosystems; oil spills (Deepwater Horizon 4.9 million barrels); pipeline leaks persistent problem; produced water contamination
  • Gas Extraction: Fracking uses millions of gallons of water; potential groundwater contamination; induced seismicity (earthquakes); flaring (burning excess gas - wasteful)
  • Refining/Processing: Energy-intensive; refineries major pollution sources; toxic waste disposal problems

Oil Spill Consequences

  • Marine Ecosystem Damage: Toxins kill fish, shellfish, marine mammals; coating animals prevents movement; impacts food webs for years
  • Coastal Communities: Fishing livelihoods destroyed; tourism collapsed; cleanup costs billions
  • Long-term Effects: Oil persists in sediments decades; bioaccumulation in food chains; genetic damage to surviving populations
  • Notable Examples: Exxon Valdez (1989, Alaska, 11 million gallons), Deepwater Horizon (2010, Gulf, 4.9 million barrels, worst US environmental disaster), Prestige (2002, Spain)

💡 Exam Tip: Fossil fuels nonrenewable; formed over millions of years. Coal = dirtiest; oil = most transportable; gas = cleanest fossil fuel. Climate impact from CO₂ (persistent); air pollution from particulates/SO₂/NOx (immediate health). Know extraction impacts (mining, drilling, fracking). Oil spills catastrophic for marine life. "Peak oil" concept = production may decline as reserves deplete. Transition away requires replacement infrastructure.

6.6 Nuclear Power

Nuclear Fission Process

Fundamental Process: Uranium-235 nucleus absorbs neutron, becomes unstable, splits into two fragments + releases 2-3 neutrons + tremendous energy (fission reaction releases ~200 MeV per atom).

Chain Reaction

  • Controlled Chain Reaction: Neutrons trigger more fission; reaction controlled by control rods (absorb neutrons); maintains steady fission rate
  • Heat Generation: Fission fragments release kinetic energy; collide with other atoms; converted to thermal energy (~350°C in reactor core)
  • Energy Production: Heat boils water → steam → drives turbines → electricity generation
  • Energy Density: 1 kg uranium-235 = energy of 3 million kg coal; ~80 million MJ/kg (incredible efficiency)
  • Thermal Efficiency: Typical nuclear plants ~33% efficient (convert 1/3 of heat to electricity); limited by thermodynamic efficiency

Advantages of Nuclear Power

  • Zero Carbon Emissions: No CO₂ during operation (only during construction); essential for climate mitigation; single largest low-carbon source
  • High Capacity Factor: ~90% (runs continuously); solar ~25%, wind ~35%, coal ~40%; most reliable baseload power
  • Small Land Footprint: ~1 km² per GW electricity (lowest of all sources); solar needs 45x more land per GW
  • No Air Pollution: No particulates, SO₂, NOx, mercury; zero health impacts from operation
  • Established Technology: 400+ operating reactors globally; 60+ years operational experience; safety record excellent (deaths/TWh among lowest)
  • Grid Stability: Baseload power balances intermittent renewables; can be paired with solar/wind to provide stable supply
  • Modern Designs: Gen III+ reactors have improved safety systems, can't melt down, produce less waste

Disadvantages and Challenges

Nuclear Waste

  • Radioactive Waste Categories: High-level waste (spent fuel rods) - dangerously radioactive 10,000+ years; low-level waste (tools, clothing) - decades to centuries
  • Storage Problem: No country successfully storing long-term high-level waste; USA planned Yucca Mountain repository cancelled; France processes waste (reduces volume but creates new waste form)
  • Temporary Storage: Spent fuel pools at reactor sites; pools require cooling; some transitioning to dry cask storage (more stable but still not long-term solution)
  • Volume: 250,000+ tonnes high-level waste accumulated globally; small volume but high hazard
  • Cost: USA estimated $100+ billion to build permanent repository; other nations estimate similar
  • Future Generations: Waste remains hazardous longer than recorded human history; ethical concern (burden on future)

Safety and Accidents

  • Statistical Safety: Deaths per TWh: nuclear 0.07 (lowest), solar 0.44, wind 0.15, coal 25 (highest); nuclear safest energy source
  • Catastrophic Potential: Rare but severe accidents possible; Three Mile Island (1979, partial meltdown, limited release), Chernobyl (1986, explosion, 4,000+ deaths estimated), Fukushima (2011, tsunami, meltdown)
  • Psychological Impact: Fear of nuclear accidents disproportionate to risk; media sensationalism; public opposition despite low statistical risk
  • Redundancy: Modern reactors have multiple independent safety systems; passive safety (natural cooling); can't accidentally melt down (Gen III+)
  • Human Error/Natural Disasters: Most accidents human error + inadequate maintenance or extreme natural events (earthquake, tsunami)
  • Decommissioning: After 40-60 year lifespan, reactors decommissioned; radioactive materials must be handled; costs $500 million+ per reactor

Economics and Construction

  • Capital Costs: $10-20 billion per reactor; nuclear costliest energy infrastructure per MW
  • Construction Time: 10-15 years typical (project delays common); long time to generate revenue
  • Operating Costs: Low (~$40/MWh) once built; costs amortized over decades
  • Financing Challenges: High upfront costs, long payback periods make financing difficult; risky for private investment; government backing essential
  • Competitive Pressure: Solar/wind costs crashed 80-90% in 10 years; nuclear costs rising; renewables now cheaper to build new capacity
  • Recent Developments: Small modular reactors (SMRs) promise lower costs, factory construction; not yet commercially available

Proliferation and Security

  • Weapons-Grade Material: Uranium enrichment (used for weapons) similar to reactor fuel production; nuclear power expansion could enable proliferation
  • Spent Fuel: Contains plutonium (weapon-usable); theft/diversion risk requires heavy security
  • Terrorism Target: Nuclear plants potential terrorist targets; designed to withstand attacks but vulnerability remains concern
  • International Safeguards: IAEA inspections and treaties restrict weapons development; non-proliferation regime generally successful but imperfect
  • Energy Security vs. Security Risk: Benefits of nuclear for climate must balance proliferation risks

💡 Exam Tip: Nuclear = zero-carbon baseload (90% capacity factor); statistically safest (lowest deaths/TWh); essential for climate mitigation. BUT: waste storage unsolved (10,000+ year hazard), high costs ($10-20B per plant), long construction, public opposition. Accidents rare but catastrophic (Chernobyl, Fukushima). Modern reactors safer. Must be paired with renewables for complete decarbonization. Know climate benefit vs. concerns tradeoff!

6.7 Energy from Biomass

Overview and Definition

Biomass Energy is energy from organic matter - plant material, agricultural waste, forestry waste, animal waste. It represents stored solar energy from photosynthesis; burning biomass releases this energy. ~4% of global primary energy comes from biomass; ~14% in developing nations (often traditional firewood for heating/cooking).

For the AP Environmental Science exam, you must understand biomass types, sustainability concerns, carbon cycle implications, air pollution, and the difference between sustainable and unsustainable biomass use.

Types of Biomass Energy

1. Wood and Forest Biomass

  • Primary Use: Heating and electricity generation; ~40% of renewable energy globally
  • Types: Firewood (traditional heating), wood pellets (compressed sawdust), wood chips (forest residue)
  • Energy Content: ~15 MJ/kg (lower than coal 24 MJ/kg due to moisture); higher moisture reduces efficiency significantly
  • Sustainability: Carbon-neutral only if regrowth replaces harvest; clear-cutting = 50-100 year carbon debt; sustainable forestry = renewable energy
  • Electricity Generation: Wood-fired power plants ~30-40% efficient; thermal plants combust wood to create steam driving turbines
  • Heating Efficiency: Wood stoves/boilers 70-90% efficient; modern systems high-efficiency; traditional open fires ~10-20% efficient (wasteful)
  • Air Pollution: Wood burning produces particulate matter, NOx, CO; indoor wood heating major indoor air pollution source (3 million deaths/year globally from indoor biomass smoke)

2. Agricultural Residues and Waste

  • Sources: Crop residue (corn stover, wheat straw, rice husks); vegetable waste; food processing waste
  • Volume: Enormous quantities annually; estimated 2+ billion tonnes agricultural waste globally
  • Advantages: Waste product (no competition with food production); free or cheap feedstock; already concentrated at farms/processing facilities
  • Uses: Direct combustion for electricity/heat; pelletization for transport; anaerobic digestion for biogas
  • Sustainability Concerns: Removing all residue depletes soil organic matter (reduces fertility, carbon storage); best practice = remove 50-70% only, leave portion for soil health
  • Energy Content: Variable 12-18 MJ/kg depending on crop; lower than coal but acceptable for local use

3. Biogas from Anaerobic Digestion

  • Process: Microorganisms decompose organic matter in oxygen-free environment; produces methane (CH₄, 60-70%) and CO₂ (30-40%)
  • Feedstock: Animal manure (primary), food waste, wastewater sludge, agricultural residue; any biodegradable organic matter
  • Energy Content: Biogas ~20 MJ/m³ (compared to natural gas 35 MJ/m³); lower but usable for electricity/heating
  • Environmental Benefit: Prevents methane escape from landfills/manure piles (methane 25-30x more potent GHG than CO₂); captures biogas for energy
  • Byproducts: Digestate (remaining solids) valuable fertilizer; reduces need for synthetic fertilizer (saves energy)
  • Farm Applications: Dairy farms with large herds produce significant biogas; can power farm operations; emerging revenue stream
  • Landfill Gas: Existing landfills produce significant biogas; capture and combustion reduces emissions; prevents greenhouse gas release
  • Wastewater Treatment: Sewage sludge digestion produces biogas; provides energy for treatment plant operation (many now energy self-sufficient)

4. Biofuels (Liquid)

  • Ethanol (First-Generation): Fermented from sugar (sugarcane, sugar beets) or starch (corn, wheat); primary biofuel globally
  • Biodiesel (First-Generation): Transesterification of oils (soybean, palm, canola); produces diesel-like fuel
  • First-Generation Problems: Competes with food crops for land; food security concerns; land use change increases emissions; variable net carbon benefit
  • EROI (Energy Return on Invested): Corn ethanol EROI ~1.3 (requires 1 unit fossil energy to produce 1.3 units ethanol energy); marginal benefit; sugarcane ethanol better EROI ~5-8
  • Deforestation Link: Palm oil biodiesel expansion drives rainforest destruction (Indonesia, Malaysia); carbon emissions from land clearing exceed carbon saved
  • Second-Generation Biofuels: Cellulosic ethanol from crop residue/wood; doesn't compete with food; better sustainability; still experimental and expensive (~3x cost of corn ethanol)
  • Blending Standards: E10 (10% ethanol gasoline blend) common in USA; E85 (85% ethanol) requires compatible engines; policy support drives adoption
  • Current Use: ~3% of global transportation fuel; growing but limited by land availability and sustainability concerns

Carbon Cycle and Sustainability

Carbon-Neutral Concept

  • Theoretical: CO₂ released during combustion = CO₂ absorbed during plant growth; net zero carbon
  • Reality: Carbon-neutral only if regrowth rate ≥ harvest rate; assumption often violated in practice
  • Time Lag: Carbon released immediately; regrowth takes decades; creates net carbon debt period
  • Land Use Change: Converting forest to plantation carbon-negative (lost forest carbon storage); must regrow on same land
  • Best Practice: Use waste biomass (doesn't require new growth); ensure regrowth; avoid high-carbon-store ecosystems (forests, peatlands)

Sustainability Red Flags

  • Deforestation: Cutting ancient forests = carbon-negative (lost old-growth storage); even replanting doesn't offset for 50-100+ years
  • Peatland Drainage: Peatlands store 2x more carbon than all forests; draining for biofuel feedstock releases stored carbon; highly carbon-positive
  • Monocultures: Biomass plantations on former biodiverse land = biodiversity loss; reduces carbon storage compared to diverse forests
  • Harvest Exceeds Regrowth: Many regions cutting faster than regrowth; net carbon loss; unsustainable
  • Food Competition: Biofuels from food crops drives food price inflation; impacts vulnerable populations
  • Processing Energy: Ethanol production energy-intensive; must use renewable energy or net carbon benefit questionable

Environmental and Health Impacts

Air Pollution

  • Particulate Matter: Biomass burning produces soot, ash; PM2.5 penetrates lungs; cardiovascular and respiratory disease
  • Indoor Air Quality: Wood heating in homes major pollution source; developing nations burn biomass indoors without ventilation; causes 3+ million premature deaths annually (WHO)
  • NOx and CO: Combustion produces nitrogen oxides and carbon monoxide; contribute to smog and health impacts
  • Volatile Organic Compounds (VOCs): Released during biomass burning; contribute to ground-level ozone formation
  • Mitigation: Modern high-efficiency biomass combustion reduces emissions; clean stove programs in developing nations; transition to other energy

Ecological Impacts

  • Deforestation: Biomass plantations replace natural forests; biodiversity loss; habitat destruction; soil degradation
  • Soil Health: Harvesting all residue removes organic matter; reduces soil carbon, fertility; requires synthetic fertilizers offsetting carbon savings
  • Water Impacts: Biomass crop monocultures use more water than native vegetation; affects groundwater; impacts aquatic ecosystems
  • Species Extinction: Rainforest conversion for palm oil/sugarcane; endemic species loss; agricultural expansion major extinction driver

💡 Exam Tip: Biomass is renewable ONLY if regrowth ≥ harvest. Waste biomass (residue, biogas) most sustainable. First-generation biofuels problematic (food competition, deforestation). Carbon-neutral claim often false due to land-use change, time lags, processing energy. Indoor biomass heating = huge air pollution problem in developing nations. Know difference between sustainable (waste residue) and unsustainable (deforestation for plantations) biomass!

6.8 Solar Energy

Overview and Technology

Solar Energy is humanity's most abundant energy resource; Earth receives ~173,000 TW solar radiation continuously (far exceeding human energy use of ~18 TW). Solar technology converts this radiation to electricity (photovoltaic) or heat (thermal). Fastest-growing energy source globally; capacity increasing ~20% annually.

For the AP Environmental Science exam, you must understand PV technology, efficiency limits, capacity factors, intermittency, storage requirements, and environmental considerations.

Photovoltaic (PV) Technology

How PV Works

  • Semiconductor Material: Silicon atoms with 4 valence electrons; adding dopants creates n-type (extra electrons) and p-type (holes) layers
  • Photon Absorption: Light photons knock electrons free from silicon atoms; electrons gain energy equal to photon energy
  • Electric Field: p-n junction creates electric field; separates free electrons toward n-layer, holes toward p-layer
  • Current Generation: External circuit allows electrons to flow; current flows through load (lights, batteries, inverter)
  • No Moving Parts: Solid-state technology; inherently reliable; 25-30 year lifespan typical
  • Voltage and Current: Single cell ~0.6V; modules string cells in series (V increases); parallel wiring increases current; inverter converts DC to AC for grid

Efficiency and Losses

  • Theoretical Maximum (Shockley-Queisser Limit): ~33% for single-junction silicon; limit due to photon energy spectrum and heat losses
  • Commercial Efficiency: Monocrystalline 20-22%, Polycrystalline 15-18%, Thin-film 10-15%; multi-junction lab cells 47%+ but too expensive for commercial use
  • Efficiency Losses: Reflection (30% light bounces off); thermalization (excess photon energy as heat); recombination (electrons lose energy); resistance losses
  • Temperature Effect: Efficiency decreases ~0.5% per °C above 25°C (STC); hot panels less efficient; cooling increases output ~10-20%
  • Dirt and Shading: Dust/dirt reduces output ~15-25%; partial shading creates reverse current, can damage cells (bypass diodes prevent)
  • System Efficiency: Overall system (panels + inverter + wiring) ~85% efficient; losses throughout: panel mismatch, inverter (95% efficient), wiring (2-3% loss)
  • Capacity Factor: Average 15-25% (vs. nameplate capacity); varies by location (25% cloudy regions, 35%+ sunny deserts)

PV Cell Types

  • Monocrystalline (Mono): Single silicon crystal; most efficient (~22%); dark color; expensive (~$0.40-0.50/W); preferred for space-limited applications
  • Polycrystalline (Multi): Many silicon crystals; less efficient (~18%); blue color; cheaper (~$0.35-0.45/W); popular for utility-scale
  • Thin-Film: Thin semiconductor layer on substrate (amorphous silicon, CdTe, CIGS); less efficient (10-15%); cheaper; lighter; flexible; poor longevity (degradation over time)
  • Perovskite: Emerging technology; potential 20%+ efficiency; cheaper manufacturing; stability issues (degrades with moisture)
  • Multi-Junction: Multiple stacked junctions targeting different wavelengths; 40%+ efficiency achieved but extremely expensive; space applications

Energy Payback and Life Cycle

  • Energy Payback Period: Time to generate energy = energy invested in production; modern panels 1-4 years (excellent!); older panels 7-8 years
  • Calculation: 25-year lifespan; payback 1-4 years = 6-25x energy return over lifetime (EROI 6-25)
  • Manufacturing Energy: Silicon purification energy-intensive; modern production more efficient; renewable electricity powering factories improves footprint
  • Carbon Payback: Time to offset manufacturing carbon; modern panels 3-4 years; cleaner grid sources faster payback
  • Recycling: 95%+ of panel materials recyclable (glass, aluminum, silicon); recycling infrastructure developing; recovers materials for new panels
  • End of Life: After 25-30 years, panel efficiency drops 20%+ (degradation ~0.5-0.8% annually); panels still produce 80%+ output; can be repowered or recycled

Solar Thermal Technology

Direct Solar Thermal

  • Flat-Plate Collectors: Water/glycol circulates through tubes absorbing solar heat; insulated box prevents radiation loss; 70-80% efficient
  • Applications: Water heating (50% of heating water demand potential), space heating, pool heating, industrial heat
  • Advantages: Simple technology; high efficiency; long lifespan (20-30 years); low maintenance; cheap ($2-5/W)
  • Disadvantages: Requires space; subject to weather; freeze protection needed in cold climates; backup heat needed for cloudy days
  • Heat Storage: Insulated tanks store thermal energy; enables use during night/cloudy periods; thermal mass cheaper than batteries

Concentrated Solar Power (CSP)

  • Technology: Mirrors/lenses concentrate sunlight to heat fluid to 300-500°C; drives turbine for electricity; essentially concentrating solar into concentrated heat
  • Types: Parabolic troughs (most common), central receiver towers, dish systems
  • Capacity Factor: 25-50% with thermal storage; excellent dispatchability (can continue generating after sunset if insulated)
  • Thermal Storage: Molten salt tanks store energy; enables 24-hour operation; valuable for grid stability
  • Advantages: Natural thermal storage; baseload capability; low operating costs; high efficiency 20-30%
  • Disadvantages: High capital costs ($2-4/W); land-intensive; requires direct beam sunlight (doesn't work in clouds); limited by location
  • Geographic Limits: Requires high direct normal irradiance; best in deserts; limited to ~30°N/S latitude bands

Intermittency and Grid Integration

Intermittency Challenge

  • Daily Cycle: Zero output at night; peaks at midday; afternoon ramp-down creates grid imbalance
  • Weather Variability: Clouds reduce output 50-75%; season affects peak times; variability different from wind (peaks different times)
  • Grid Mismatch: Solar peaks midday (low demand); evening peak requires other sources; requires flexible backup
  • Ramp Rates: Fast changes in cloud cover create supply swings; grid frequency must stay 59.5-60.5 Hz; challenges system operators
  • Solution Approaches: Geographic diversity (multiple solar sites reduce aggregate variability), batteries, demand response, interconnection with other grids

Storage Solutions

  • Battery Storage: Lithium-ion batteries 85-95% efficient; costs falling 90% in 10 years; now <$100/kWh (approaching grid parity); essential for high-solar grids
  • Thermal Storage: Solar thermal systems store heat naturally; molten salt, PCM (phase change materials); 2-4 hour discharge typical
  • Pumped Hydro: Existing technology; 70-85% efficient; limited by geography; can provide many hours discharge
  • Hydrogen/Fuel Cells: Convert excess solar to hydrogen; long-term storage; inefficient (40-50% round trip) but scalable
  • Grid-Scale Storage Needs: 1-4 hour storage for daily cycle (batteries good); seasonal storage harder (winter shortage in northern regions)
  • Complementarity: Solar + wind combined more stable (wind often night/winter); reduces storage needs 50%+

Economics and Deployment

Cost Trajectory

  • Dramatic Cost Decline: Module costs fell 90% since 2010 ($370/W to $40/W); system costs ~$1-2/W installed
  • Levelized Cost of Electricity (LCOE): Solar now $30-60/MWh (cheapest in many regions); wind $30-80/MWh; coal $60-120/MWh; natural gas $40-100/MWh
  • Learning Curve: 20% cost reduction per doubling of cumulative capacity; continuing trend expected
  • Factors Driving Decline: Manufacturing scale, efficiency improvements, supply chain competition, automation
  • Future Potential: $20-40/MWh possible by 2030; solar likely cheapest electricity source globally
  • Balance of System Costs: Panels now <50% of cost; inverters, wiring, installation, permits remaining costs; installation labor significant

Deployment Scale

  • Current Capacity: ~1 TW solar capacity globally (2024); doubling every 3-4 years
  • Electricity Generation: Solar produced ~5% of global electricity (2024); projected 20-30% by 2050
  • Land Requirements: ~100 m² per kW nameplate capacity (varies with mounting, efficiency); 100 GW solar = ~10,000 km² land (same as large city)
  • Rooftop Potential: Existing roof area globally sufficient for 1+ TW solar without competing for land
  • Desert Potential: 1% of world's deserts covered in solar = current global electricity demand (DESERTEC concept); technically feasible
  • Geographic Distribution: Solar potential widely distributed; every continent can deploy; enables energy independence

💡 Exam Tip: Solar efficiency ~20% commercial (limit 33% Shockley-Queisser); capacity factor 15-25% (varies by location). PV most reliable technology (no moving parts, 25-30 year lifespan). Energy payback 1-4 years (EROI 6-25x excellent). Intermittency main challenge (zero at night, varies with clouds); requires storage or flexible backup. Costs fell 90% in 10 years; now cheapest electricity in many regions. Know PV vs. thermal (thermal better for heat, PV for electricity)!

6.9 Hydroelectric Power

Principles and Physics

Hydroelectric Power converts gravitational potential energy of water into mechanical energy (turbine rotation) then electrical energy. Water from higher elevation flows downward (or is stored and released), driving turbines. ~6% of global electricity from hydro (~16% of renewable electricity). Most efficient technology available (85-90%).

Energy Calculation

Potential Energy: PE = mgh (mass × gravity × height)

Power Output: P = ηρgQH (efficiency × density × gravity × flow rate × head)

  • Head (H): Vertical distance water falls; higher head = more power; small high-head plant can outproduce large low-head plant
  • Flow Rate (Q): Volume of water per time; larger rivers higher flow = more power; flow varies seasonally (wet vs. dry season)
  • Efficiency (η): 85-90% typical; excellent; limited mainly by friction and leakage
  • Example: 100 m³/s at 100 m head = ~100 MW (order-of-magnitude calculation: ρgh = 1000 × 10 × 100 = 1 MJ/m³; flow rate gives 100 MJ/s = 100 MW)

Hydroelectric Types

Run-of-River Systems

  • Design: No reservoir; turbines in river channel; water continuously flows through
  • Advantages: Minimal environmental disruption (no damming); maintains natural flow; fish can migrate past turbines (with screens); no large reservoir
  • Disadvantages: Output follows seasonal flow (wet season high, dry season low); no storage for flexibility; can't store energy for peak demand
  • Capacity Factor: 40-60% (varies with seasonal flow pattern); predictable in watersheds with steady discharge
  • Turbine Mortality: Fish passage through turbines causes 10-30% mortality (best available, but still problematic)
  • Installation: Faster construction than dams; easier environmental approval (less habitat damage); emerging preference globally

Reservoir/Dam Systems

  • Design: Large dam creates reservoir; stores water; operator controls release for electricity generation
  • Advantages: Flexible dispatch (can release water anytime); multiple uses (irrigation, water supply, flood control, recreation); can provide baseload power with storage; high capacity factor 60-90%
  • Disadvantages: Massive environmental disruption; blocks fish migration (50+ km passable rivers blocked); flooding of valley (habitat loss, archaeological sites); displacement of people (millions historically)
  • Methane Emissions: Submerged vegetation decomposes anaerobically; produces methane (25-30x more potent GHG than CO₂); tropical reservoirs particularly bad (~200% increase in GHG if accounting for methane); partially negates climate benefit
  • Sedimentation: Dams trap sediment (100+ million tonnes annually globally); downstream delta starves of sediment (erosion); reservoir fills with sediment (200-300 year lifetime typical)
  • Fish Impacts: Upstream - can't migrate to spawning grounds; downstream - water temperature/oxygen changes; reservoir - predator habitat; ~30-40% salmon mortality at dams
  • Social Impacts: Three Gorges Dam (China) displaced 1.3 million people; Aswan Dam flooded entire civilization's homeland; land acquisition & resettlement costly and controversial

Pumped Storage Hydroelectricity

  • Technology: Two reservoirs at different elevations; at night (low demand, cheap electricity), pump water from lower to upper; during day (high demand), release upper water through turbines
  • Function: Acts as giant battery; stores energy as potential energy; round-trip efficiency 70-85% (loses 15-30% to pumping friction)
  • Capacity Factor: 20-50% (not continuously operating; cycles based on demand); provides energy storage, not new generation
  • Grid Support: Provides frequency regulation, load following, peak capacity; essential for integrating variable renewables
  • Advantage of Hydro Storage: Multiple-hour discharge capability (4-24 hours typical); batteries typically 2-4 hours; hydro best for long-duration storage
  • Global Capacity: ~160 GW pumped storage globally; growing fast; most cost-effective grid storage technology at scale
  • New Projects: Emerging offshore pumped storage (use ocean level differences); potential massive scale

In-Stream / Tidal Hydroelectric

  • In-Stream Turbines: Devices installed in river channel without dam; water flows around; minimal fish impact; early-stage technology
  • Tidal Energy: Uses tidal flow in bays/straits; turbines spin as tides flow; predictable (unlike solar/wind); emerging technology; limited sites (strong tidal currents needed)
  • Wave Energy: Waves on ocean surface; devices extract energy; high energy density but harsh environment; not yet commercial
  • Development Stage: All emerging; potential but not yet competitive with conventional hydro; environmental impacts uncertain

Environmental and Social Considerations

Ecosystem Impacts

  • Migratory Species: Anadromous fish (salmon, shad) swim upriver to spawn; dams block migration; population collapse (Pacific Northwest salmon nearly extinct); fish ladders help but not 100% effective
  • Downstream Erosion: Reservoir traps sediment; downriver delta starved; Mediterranean deltas, Nile Delta, Mekong Delta all losing land due to upstream dams
  • Temperature Changes: Deep water releases from dams colder than natural water; impacts cold-intolerant species; algae balance disrupted
  • Oxygen Depletion: Reservoir stratification; deep water anoxic; releases anoxic water downstream; kills fish and aquatic organisms
  • Riparian Zone Loss: Dams prevent floods; floodplain vegetation depends on periodic flooding; loss of biodiversity habitat
  • Invasive Species: Reservoirs act as traps; invasive aquatic plants take over; food web disruption

Social and Cultural Impacts

  • Displacement: Large dams displace millions (Three Gorges 1.3M, Aswan 100k, Itaipu 42k); people lose homes, agricultural land, cultural heritage
  • Indigenous Rights: Dams often on indigenous lands; destroy ancestral territories; violate rights; inadequate compensation
  • Resettlement Costs: Expensive and often fails; communities struggle economically; cultural disruption; resentment toward project
  • Transboundary Conflicts: International rivers; dams in upstream country affect downstream; water security concerns; geopolitical tensions (Turkey-Syria-Iraq over Euphrates; Egypt-Sudan-Ethiopia over Nile)
  • Benefit Distribution: Often centralized hydropower benefits distant cities while local communities bear environmental costs; equity concerns

Global Hydroelectric Situation

  • Current Capacity: ~1.4 TW global hydroelectric capacity; produces ~4,200 TWh annually (~16% of global electricity)
  • Best Hydropower Countries: Canada (95 GW), USA (85 GW), Brazil (75 GW), Russia (50 GW), India (50 GW); others like Norway (15 GW) punch above weight (30% of electricity)
  • Hydropower-Dependent Nations: Iceland (85% hydro), Norway (95% hydro/wind), Costa Rica (65% hydro); vulnerable to droughts
  • Future Expansion Limited: ~40% of economically viable potential already exploited; remaining sites often in protected areas or face environmental opposition; little room for growth in developed nations
  • Developing Nation Growth: China, India, Brazil continuing expansion; Africa and Southeast Asia significant potential; but environmental concerns growing
  • Climate Change Impacts: Hydrological cycles changing; precipitation patterns shifting; drought years reduce generation (Australia, Chile, Brazil all experienced hydro shortages); reliability declining
  • Paradox: Hydro is clean energy when operating but massive environmental/social costs upfront; questionable sustainability for new projects in pristine areas

💡 Exam Tip: Hydroelectric most efficient (85-90%); can be baseload (with storage) or variable (run-of-river). Highest capacity factor (60-90% reservoir, 40-60% run-of-river). Power = ηρgQH (head and flow critical). Massive environmental impacts: fish migration blocked, sediment trapping, methane from tropical reservoirs, ecosystem disruption. Social impacts: displacement (millions historically), indigenous rights, transboundary conflicts. Not always "clean energy" - depends on context. Know tradeoffs!

6.10 Geothermal Energy

Heat Source and Distribution

Geothermal Energy comes from Earth's internal heat. Core temperature ~5,200°C; heat flows outward through conduction. Temperature increases ~25°C per km depth (geothermal gradient); in tectonically active areas 100°C+ per km. Radioactive decay of uranium, thorium, potassium in Earth's crust provides continuous heat generation (~47 TW total flow; ~0.03 TW could theoretically be harvested).

Geothermal Reservoirs

  • Formation: Hot rock or water at depth; fractures allow hot water/steam to circulate; suitable depths 2-3 km typically
  • Types: Hydrothermal (hot water/steam reservoirs, best for electricity); Geopressured (high-pressure hot water); Radiogenic (dry rock at depth, requires enhancement)
  • Location: Limited to geothermally active zones: Ring of Fire (Pacific Rim), East African Rift, Iceland, New Zealand, Mediterranean, Yellowstone region
  • Resource Quality: High-grade resources (200°C+) good for electricity; medium-grade (100-200°C) for direct heating; low-grade (50-100°C) limited uses
  • Reservoir Lifetime: Decades to centuries; recharge rate determines sustainability; risk of cooling if extraction too fast; some successful re-injection schemes maintain temperature

Geothermal Power Generation

Electricity Generation

  • Process: Wells drill to depth; hot water/steam rises naturally or is pumped; steam drives turbine; condenser cools exhaust steam back to water; water injected back into reservoir
  • Thermal Efficiency: Low (~10%); heat rejected to environment; limited by thermodynamic cycle (Carnot efficiency limited by temperature difference)
  • Capacity Factor: Excellent 70-90% (similar to nuclear, higher than most others); runs continuously; highly reliable
  • Plant Lifespan: 25-50 years typical; reinjection extends resource life; successful field management maintains production decades+
  • Dispatchability: Good load-following capability; can increase/decrease output by controlling steam release
  • Global Capacity: ~15 GW geothermal electricity generation; produces ~100 TWh annually (~0.3% of global electricity); Iceland 30%, Philippines 20%, USA 10%, Mexico 8%

Direct Use Applications

  • Heating (Primary Use): Direct use geothermal ~3x electricity generation globally; heating water for homes/greenhouses/industrial
  • Efficiency: 70-90% efficient (heat transfer, not thermodynamic conversion); much better than electricity generation
  • Applications: Space heating (Iceland 30% of heating), hot water, bathing, agriculture (greenhouses year-round), fish farming, food processing, paper industry
  • Payback: Quick payback (5-10 years) due to high efficiency; low operating costs; savings compelling economically
  • Location Advantage: Geothermal heating enables countries to reduce fossil fuel dependence; Iceland example (drops oil imports, high renewable %)
  • Cascade Use: Lower temperature water after electricity used for heating; maximizes resource utilization

Enhanced Geothermal Systems (EGS)

Technology and Potential

  • Concept: Artificial fracturing in hot but dry rock to create permeability; hydraulic fracturing like oil/gas extraction; water circulates through fractured rock
  • Advantage: Potentially usable anywhere with sufficient depth; not location-limited like natural geothermal; massive technical potential
  • Development Status: Early-stage technology; pilot projects in France, Australia, Japan; not yet commercially viable; costs too high
  • Technical Challenges: Drilling deep (4-5 km) expensive; fracturing engineering complex; monitoring/control uncertain; well lifetime/productivity questions
  • Economic Challenges: High capital costs; long exploration phase; high risk (wells may not work); financing difficult
  • Environmental Concerns: Induced seismicity (microearthquakes); potential groundwater contamination; pressure on host rock
  • Timeline: Probably 10-20 years before EGS economically competitive; may revolutionize geothermal if successful

Global Potential

  • Conventional Geothermal: ~70-100 GW potential; currently ~15 GW deployed; most economical sites developed; expansion to ~30-50 GW possible
  • EGS Potential: Theoretically unlimited; could provide significant baseload power globally if technology matures; estimates 100+ GW possible by 2050
  • Regional Advantage: Not possible everywhere (drilling to 5 km in cold rock expensive); best in regions with reasonable depth to high-temperature rock
  • Integration: Geothermal baseload pairs with variable renewables (solar/wind) to provide stable grid

💡 Exam Tip: Geothermal baseload (70-90% capacity factor); zero emissions; clean technology. BUT: location-limited (Ring of Fire, Iceland, NZ); not solution for most countries. Direct heating more efficient (70-90%) than electricity (10%). EGS emerging technology - could expand potential but not yet commercial. Know current capacity (~15 GW) vs. potential (70-100 GW conventional, 100+ GW EGS). Induced seismicity concern for EGS. Reinjection extends reservoir lifetime!

6.11 Hydrogen Fuel Cell

Overview and Fuel Cell Technology

Hydrogen Fuel Cells generate electricity through electrochemical reaction: hydrogen gas combines with oxygen; produces water and energy. Zero direct emissions (only water); clean technology. Currently <1% of energy use; emerging technology being heavily researched/promoted for decarbonization of hard-to-electrify sectors.

Fuel Cell Operation

  • Electrochemical Process: H₂ enters anode; splits into 2 protons + 2 electrons; electrons flow through external circuit (creating current); protons cross electrolyte; O₂ at cathode accepts electrons + protons; forms H₂O
  • Types: PEM (proton exchange membrane) ~80% current use, SOFC (solid oxide), PAFC (phosphoric acid), alkaline
  • Efficiency: Electrochemical conversion 60-70%; better than combustion engines 40%; electrical efficiency not thermodynamically limited like heat engines
  • Advantages: No pollutants (only water); quiet operation; responsive (can ramp up/down quickly); modular (scalable)
  • Disadvantages: Hydrogen production energy-intensive; storage difficult; infrastructure absent; cost high; catalysts (platinum) expensive
  • Durability: PEM cells 3,000-5,000 hours typical (vehicles 5-10 years); requires replacement; cost factor

Hydrogen Production

Steam Methane Reforming (SMR)

  • Process: Natural gas (CH₄) + steam → CO + H₂; CO + water → CO₂ + H₂
  • Current Reality: 95% of hydrogen produced this way; cheap (~$1-2/kg); well-established infrastructure
  • Emissions: Produces CO₂ (0.2 kg CO₂ per kg H₂); "grey hydrogen"; carbon-negative
  • Improvement: Blue hydrogen: SMR with carbon capture (~90% CO₂ captured); reduces emissions 80-90%; more expensive
  • Problem: If hydrogen from fossil gas, not truly zero-emission; defeats climate purpose unless carbon captured

Electrolysis

  • Process: Electric current splits water (H₂O) into hydrogen (H₂) and oxygen (O₂); "green hydrogen" if powered by renewables
  • Efficiency: ~65% electrical efficiency (electrical energy to chemical energy); thermodynamic efficiency high, but grid losses add up
  • Cost: Green hydrogen ~$6-10/kg (current); grid electricity expensive; needs cheap renewable electricity to compete
  • Grid Application: Absorbs excess renewable electricity; stores energy as hydrogen; recovers via fuel cell (40-50% round-trip efficiency: electricity → H₂ → electricity)
  • Advantage: Creates long-term energy storage; can supply weeks/months (battery limited to hours)
  • Scaling: Production increasing; costs projected to fall as renewables cheaper; could become cost-competitive by 2030-2040
  • Carbon Payback: Green hydrogen carbon payback depends on grid electricity source; renewable-powered only ~1-2 years

Other Production Methods

  • Biomass Gasification: Heat biomass without oxygen; produces hydrogen-rich gas; clean feedstock produces low-carbon H₂
  • Photoelectrochemical: Direct water splitting using sunlight; research-stage; mimics photosynthesis
  • Biological: Algae/bacteria produce hydrogen under certain conditions; emerging; not yet commercial
  • Nuclear-powered Electrolysis: High-temperature nuclear produces hydrogen; zero-carbon if reactor safety assured

Hydrogen Storage and Transport

Storage Challenges

  • Low Density: Hydrogen gas very low density; high volume needed even for modest energy storage
  • Compressed Gas: Storage at 350-700 bar; expensive, heavy tanks required; safety concerns (hydrogen highly flammable)
  • Liquid Hydrogen: Cryogenic (-253°C); requires expensive insulation; 30% energy lost in liquefaction process
  • Chemical Storage: Binding hydrogen in ammonia (NH₃) or formic acid (HCOOH); easier transport; must release hydrogen (energy cost)
  • Material Storage: Metal hydrides, carbon nanotubes; research-stage; not yet practical
  • Reality: No ideal solution yet; limits hydrogen's practical use; storage/transport major cost

Transport and Distribution

  • Pipeline: Existing natural gas pipelines could carry hydrogen blend (up to 20%); hydrogen-only pipelines expensive to build
  • Truck/Rail: Compressed or liquid hydrogen; expensive; safety-critical; expensive infrastructure
  • Sea Transport: Liquid hydrogen or carriers; major projects planned (Saudi Arabia to Japan); enables international trade
  • Infrastructure Gap: Almost no hydrogen distribution infrastructure; requires massive investment; chicken-and-egg problem
  • Economic Barrier: Transport costs significant; limits hydrogen to high-value applications

Applications and Future Role

Current and Near-Term Uses

  • Industrial: 95% of hydrogen currently used in ammonia (fertilizer) and petroleum refining; economic value established
  • Vehicles: FCVs (fuel cell vehicles) emerging; Toyota Mirai, Hyundai Nexo available; ~20,000 FCVs globally; limited by hydrogen stations (~400 globally)
  • Heavy Transport: Trucks, buses, trains; hydrogen better than batteries (weight, range); China, Europe building hydrogen truck networks
  • Industry: High-temperature heat for steel (direct reduction), cement, chemicals; difficult to decarbonize other ways
  • Aviation/Maritime: Emerging; hydrogen synthetic fuels (e-fuels) under development; can use existing infrastructure

Barriers and Challenges

  • Cost: Green hydrogen not yet competitive with fossil hydrogen or alternatives; needs government support/subsidies
  • Infrastructure: Chicken-and-egg: vehicles won't be bought without hydrogen; stations not built without vehicles; requires coordinated investment
  • Efficiency: Well-to-wheel efficiency 40-50% (worse than battery electric 70-80%); less efficient for personal vehicles
  • Hydrogen Embrittlement: Hydrogen makes steel brittle; existing pipelines/equipment can't easily convert
  • Safety Perception: Hydrogen flammable; public concern about safety; incidents feed "hydrogen is dangerous" perception (though statistically safe)
  • Competing Technologies: Battery electric for vehicles faster/cheaper to deploy; needs less new infrastructure

💡 Exam Tip: Hydrogen zero emissions (only water); 60-70% efficient fuel cell. BUT: 95% currently produced from fossil fuels (grey); green hydrogen still expensive (~$6-10/kg). Electrolysis promising for renewable-powered production. Storage/transport major challenges (low density, no infrastructure). Best for hard-to-electrify sectors (aviation, heavy industry); less efficient than battery-electric for vehicles. Infrastructure barrier (chicken-and-egg). NOT ready-now technology - 10-20 year timeline likely. Industrial hydrogen use well-established; transportation emerging.

6.12 Wind Energy

Physics and Power Generation

Wind Energy captures kinetic energy of moving air. Wind powered by solar heating (unequal warming); Coriolis effect shapes patterns. ~8% of global electricity from wind (2024); fastest-growing after solar; capacity doubling every 3-4 years.

Wind Power Calculation

Power Formula: P = ½ρAv³

  • ρ (rho) = air density (~1.2 kg/m³ at sea level); higher density at lower elevation = more power
  • A = rotor swept area (πr²); larger rotor captures more wind; doubling rotor diameter = 4x power (quadratic relationship)
  • v³ (velocity cubed) = CRITICAL! Power proportional to wind speed cubed; small wind increase = huge power increase (double wind speed = 8x power)
  • Example: 10 m/s wind = 600 W/m²; 12 m/s wind = 1,036 W/m² (73% increase); 15 m/s wind = 2,025 W/m² (238% increase)
  • Cut-in Speed: ~3-4 m/s minimum wind to start generating; ~1-2 W/m²
  • Rated Speed: ~12-15 m/s; turbine reaches nameplate capacity
  • Cut-out Speed: ~25 m/s (storm winds); turbine shuts down to prevent damage

Turbine Types and Deployment

Onshore Wind

  • Deployment: Most common; ~95% global capacity onshore; wind farms on land
  • Turbine Size: 3-5 MW typical modern onshore; 100-150 m hub height; blade length 40-60 m
  • Capacity Factor: 35-45% average (varies by location); poor sites 20-25%, excellent sites 50%+
  • Cost: ~$1-2/W installed; lower than solar in most regions; electricity ~$40-80/MWh LCOE
  • Land Use: 40-50 acres per MW capacity; allows agricultural coexistence; sheep can graze under turbines
  • Location Drivers: Wind speed critical; coastal areas, plains, ridge tops preferred; jet stream areas in temperate zones
  • Growth: Rapidly expanding globally; USA, China, India leading installations

Offshore Wind

  • Deployment: Growing rapidly; ~5% of global capacity currently; concentrated in Northern Europe (40% global offshore capacity)
  • Turbine Size: Larger (10-15+ MW units emerging); taller hub heights (200+ m); massive rotor diameters (220+ m)
  • Capacity Factor: 40-50% (stronger, more consistent winds); better than onshore
  • Cost: ~2-4/W installed (2-3x onshore); offshore infrastructure expensive; LCOE $50-120/MWh
  • Advantages: Higher capacity factor; no land-use conflicts; stronger winds offshore; cooling benefits (power output higher in cool water)
  • Disadvantages: Extreme cost; harsh environment; maintenance difficult; marine ecosystem impacts; fishing conflicts; installation vessels complex
  • Floating Offshore: Emerging technology; turbines on floating platforms; enables deep water; expensive but potential for massive expansion
  • Future Trend: Costs falling rapidly; offshore becoming economically competitive; exponential growth expected

Turbine Design and Evolution

  • Blade Design: Aerodynamic optimization critical; airfoil shapes, pitch control, yaw to face wind
  • Efficiency: Betz limit 59% theoretical maximum; practical turbines achieve 35-45%; limited by blade design, wind shear, turbulence
  • Mechanical Systems: Gearbox converts slow blade rotation (~15 rpm) to fast generator rotation (1,000-1,800 rpm); direct-drive turbines eliminate gearbox (more efficient, simpler)
  • Lifespan: 20-25 years typical; gearboxes require maintenance; main bearings last entire life if properly designed
  • Decommissioning: Turbines removed after end-of-life; 80%+ recyclable (steel, aluminum); blade disposal challenging (fiberglass/composites); some repowering (replace turbine, keep foundation)
  • Size Trend: Continuously increasing; economies of scale; fewer larger turbines replacing many small ones

Intermittency and Grid Integration

Wind Variability

  • Daily Variation: Wind patterns shift daily; output unpredictable; can swing 50% hour-to-hour
  • Seasonal Patterns: Wind often stronger in winter (northern hemisphere); varies geographically (coastal vs. inland)
  • Complementarity: Wind often strong when solar weak (night, winter, cloudy days); combination reduces overall variability 30-50%
  • Predictability: Weather forecasts enable prediction 6-24 hours ahead; helps grid operators prepare
  • Ramp Rates: Output can change 50% in 1-2 hours with wind fronts; challenges grid frequency control (must maintain 59.5-60.5 Hz)
  • Solution Approaches: Geographic diversity (many wind farms = smoother aggregate output), flexible backup (natural gas plants can ramp quickly), demand response, energy storage

Grid Services

  • Frequency Regulation: Wind turbines can provide frequency support; helps stabilize grid
  • Reactive Power: Power electronics enable grid support; sophisticated modern turbines provide services beyond electricity
  • Voltage Support: Can help regulate voltage on transmission lines
  • Inertia Provision: Synchronous machines provide inertia; wind lacks this; concern for low-inertia grids
  • Future Role: Ancillary services from wind increasingly important as renewable penetration rises

Environmental and Social Impacts

Wildlife Impacts

  • Bird Mortality: ~200,000-600,000 bird deaths/year in USA from turbines; low compared to cats (2+ billion), vehicles (200 million), but raptors overrepresented
  • Bat Mortality: ~200,000-900,000 bats/year USA; pressure-related trauma from passing turbines; vulnerable species affected
  • Mitigation: Radar monitoring detects approaching birds/bats; turbines can shut down; timing restrictions (avoid migration); blade color impacts bird detection
  • Habitat: Minimal habitat loss during operation; minimal footprint during construction if planned carefully
  • Marine Impacts: Offshore impacts on fish, marine mammals less understood; electromagnetic fields from cables concern; noise pollution underwater
  • Perspective: Wildlife impacts real but modest compared to other energy sources; habitat loss from fossil fuel extraction far greater

Social Acceptance

  • Noise: Modern turbines ~35-45 dB at distance; complaints from nearby residents; setback distances help (typically 300-500 m minimum)
  • Visual Impact: Tall, visible structures; "visual pollution" complaints; scenic area opposition; sometimes overstated
  • Property Values: Studies show minimal impact overall; some property value decrease near turbines, other areas increase (renewable reputation)
  • Public Support: Generally favorable (70-80% support); NIMBYism in some areas ("Not In My Back Yard")
  • Community Benefits: Local tax revenue, land lease payments to farmers, job creation during construction/maintenance
  • Solution: Community engagement, transparent process, fair benefit-sharing improves acceptance

Global Deployment and Future

  • Current Capacity: ~1 TW global wind capacity (2024); ~5,000 TWh annual generation (~8% of global electricity)
  • Growth Rate: Capacity doubling every 3-4 years; fastest-growing after solar
  • Top Countries: China (40% global capacity), USA (20%), Europe (15%), India (8%), Brazil (4%)
  • Cost Decline: Fell 70% in 15 years; now competitively priced with fossil generation in most regions
  • Future Potential: 20-30% of global electricity by 2050 projected; requires offshore expansion and storage solutions
  • Manufacturing Supply Chain: Blades (Denmark, Spain, USA), turbines (multiple countries), towers (steel mills)
  • Research Directions: Larger turbines (20+ MW), floating offshore, direct-drive, hybrid wind-solar farms
  • Key Challenge: Grid integration with high penetration; requires storage, flexible backup, smart grid technologies

💡 Exam Tip: Wind power P = ½ρAv³ (velocity cubed = critical, small wind change = huge power difference). Capacity factor onshore 35-45%, offshore 40-50%. Betz limit 59% theoretical; practical 35-45% achieved. Intermittency main challenge (wind variable, unpredictable); geographic diversity + storage solutions needed. Environmental impacts: bird/bat mortality (real but manageable), minimal habitat loss during operation. Social: noise/visual concerns; community engagement helps. Know cost trajectory (fell 70% in 15 years). Currently fastest-growing energy source globally!

6.13 Energy Conservation

Definition and Importance

Energy Conservation encompasses both energy efficiency (using less energy for same output through better technology) and demand management (reducing demand through behavior change or activity reduction). Most cost-effective climate mitigation strategy; potential for 20-30% global energy reduction with existing technology. Faster and cheaper than deploying new generation capacity.

For the AP Environmental Science exam, you must understand efficiency improvements by sector, cost-benefit analysis, barriers to adoption, and the rebound effect limiting total savings.

Efficiency by Sector

Building Sector (Residential/Commercial) - Largest Potential

  • 30-50% Savings Potential: Buildings responsible for ~30% of energy use; huge efficiency opportunity
  • Heating/Cooling: ~50% of building energy; insulation improvements reduce 20-30%; wall/roof/window upgrades critical
  • Windows: Single-pane to triple-glazed + low-emissivity coating = 50-70% reduction in heat loss; energy payback 5-10 years
  • HVAC Systems: Modern high-efficiency systems 15-20% more efficient; programmable/smart thermostats 10-15% savings; heat recovery ventilation captures waste heat
  • LED Lighting: 80-90% less energy than incandescent; 10-15 year lifespan; payback 1-2 years; now default choice
  • Appliances: Refrigerators 80% more efficient than 1990s models (same function, far less energy); washing machines, dishwashers similarly improved; Energy Star standards drive efficiency
  • Hot Water: Insulated pipes, solar thermal, heat pump water heaters reduce energy 30-50%
  • Building Envelope: Air sealing prevents draft (infiltration); weatherstripping, caulking cheap; 10-15% savings possible
  • Cost Economics: Many upgrades pay for themselves in 3-7 years; offer good return on investment

Industrial Sector - 20-30% Potential

  • Energy-Intensive Processes: Steel (30 MJ/kg), cement (7 MJ/kg), chemicals; efficiency improvements significant impact
  • Motor Systems: Electric motors use 65% of industrial electricity; efficient motors 3-5% better; VFDs (variable frequency drives) reduce power 20-50% for variable-load applications
  • Compressed Air: ~10% of industrial electricity; leaks waste 20-30% in average systems; simple leak detection/repair saves money
  • Waste Heat Recovery: Industrial processes produce heat wasted; capturing for building heating, preheating inputs saves 15-30%
  • Process Optimization: Better scheduling, less idle time, improved controls reduce energy 10-20%
  • Cost Economics: Many upgrades have 2-4 year payback; economic incentive already present but capital constraints limit adoption
  • Barriers: High capital cost, uptime requirements, technical expertise needed, split incentives (engineer wants uptime, CFO wants investment)

Transportation Sector - Limited But Growing

  • Vehicle Efficiency Standards: CAFE (Corporate Average Fuel Economy) standards drive improvement; modern vehicles 2-3x more efficient than 1980s per kilometer
  • Lightweight Materials: Aluminum, carbon fiber, advanced steel reduce weight 10-20%; 5-10% fuel savings
  • Aerodynamics: Better streamlining, underbody covers reduce drag 5-15%; fuel savings 2-5%
  • Low-Rolling-Resistance Tires: 3-5% fuel savings; cost minimal
  • Hybrid/Electric Vehicles: 30-50% reduction in fuel/energy use vs. conventional; rapidly becoming cost-competitive
  • Behavioral Changes: Driving less, carpooling, public transit, active transport (walking/cycling); biggest impact but behavior change slow
  • Urban Planning: Dense development reduces travel distances; public transit accessibility critical
  • Challenge: Transportation efficiency improvements offset by more driving (rebound effect); electric cars enable more driving

Behavioral Conservation Strategies

Simple Actions

  • Lower Thermostat: 7°C reduction = ~10% energy savings; most people comfortable at ~19°C vs. 22°C
  • Shorter Showers: 5-minute reduction saves ~50 L hot water; significant daily energy reduction
  • Phantom Load Reduction: Devices in standby mode use 5-10% of household electricity; power strips eliminate standby draw
  • Laundry: Washing in cold water saves heating energy; air-dry clothes instead of dryer saves ~90% of appliance energy
  • Lighting: Turn off lights when leaving room; use natural daylight when possible
  • Total Potential: ~5-10% household energy savings from behavioral changes; modest but achievable with habit formation

Smart Metering and Feedback

  • Real-Time Feedback: Households with smart meters + real-time electricity display reduce consumption 15% just from awareness
  • Behavioral Economics: Social comparison (showing neighbors' usage) motivates conservation; loss aversion drives people to reduce excess
  • Gamification: Challenges, competitions, rewards for reducing usage boost engagement
  • Time-of-Use Pricing: Higher prices during peak hours incentivize shifting demand to off-peak; reduces need for generation capacity
  • Automation: Smart homes automatically optimize based on occupancy, weather, price signals
  • Demand Response: Utilities can temporarily reduce power (dim lighting, raise AC setpoint) during grid stress; keeps lights on while reducing demand

The Rebound Effect

How Rebound Effect Works

  • Mechanism: Efficiency improvements reduce effective energy price; lower cost encourages more use; consumption increases offsetting part of savings
  • Example 1 - Insulation: Better insulation reduces heating costs; people respond by warming house more (19°C → 21°C); some savings offset
  • Example 2 - Car Efficiency: Efficient car cheaper to drive per km; people may drive more; potential cross-travel (flights replace driving if budgets allow)
  • Example 3 - LED Lighting: Cheap to operate; people leave lights on longer; not full 80% savings realized
  • Direct Rebound: Increased consumption of same service (heating, driving); ~10-30% typical offset
  • Indirect Rebound: Money saved spent on other energy-consuming goods/services; ~10-20% offset
  • Economy-Wide Effect: Complex macroeconomic impacts; efficiency → cheaper services → economic growth → more consumption; harder to quantify
  • Total Effect: Studies suggest 10-30% of theoretical efficiency savings offset by rebound; efficiency still delivers net savings but not 100% of potential

Implications

  • Still Valuable: Even with rebound, efficiency delivers 70-90% of theoretical savings; major emissions reductions
  • Combined Approach: Efficiency alone insufficient; must pair with carbon pricing (makes consumption more expensive even if more efficient) or demand management
  • Policy Implications: Price signals essential alongside efficiency standards; otherwise rebound fully negates efficiency gains
  • Cultural Shift: Need values change beyond efficiency; sufficiency/enough concept important for deep decarbonization

Barriers to Conservation Adoption

Economic Barriers

  • High Capital Cost: Upfront investment substantial ($5,000-20,000 for building retrofits); limits adoption despite payback period
  • Financing Constraints: Poor households lack capital for investments; unable to access benefits even when economically sensible
  • Split Incentives: Landlords don't benefit if tenants pay energy bills (no investment incentive); tenants can't invest in rental property
  • Discount Rate: Individuals discount future savings; 3-year payback doesn't compete with other investment opportunities offering higher immediate returns
  • Energy Poverty: Low-income households struggling with current bills; can't afford efficiency upgrades; trapped in high-cost/inefficient buildings

Behavioral and Information Barriers

  • Information Gap: Consumers unaware of efficiency options, payback periods, or availability of programs
  • Complexity: Multiple options confusing; hard to evaluate best choice; decision paralysis
  • Inertia: Status quo bias; people stick with familiar products even if suboptimal; resistance to change
  • Habit Formation: Behavior change difficult; people revert to old habits without consistent reinforcement
  • Trust Issues: Skepticism of claims (greenwashing); doubt about actual energy savings; requires proof

Policy Solutions

  • Building Codes/Standards: Mandate efficiency levels; eliminates worst performers; levels playing field for manufacturers
  • Appliance Labels: EnergyGuide/Energy Star labels enable comparison; drive market toward efficiency
  • Rebates/Incentives: Reduce upfront cost; ease adoption; can target low-income populations
  • Financing Programs: On-bill financing, PACE (Property Assessed Clean Energy); enable investment despite capital constraints
  • Education Campaigns: Raise awareness; explain payback periods; overcome information barriers
  • Contractor Training: Ensure quality installation; builds consumer confidence
  • Rental Property Regulations: Require landlord efficiency investment; protects tenants from energy poverty

Global Potential and Outlook

  • Technical Potential: 20-30% global energy reduction with existing technology; achievable within 15-20 years with aggressive policy
  • Cost-Benefit: Net economic benefit; efficiency investments save money long-term; payback periods typically 3-10 years
  • Co-Benefits: Improved comfort (better insulation), health (better ventilation), resilience (efficient buildings tolerate disruptions better)
  • Employment: Efficiency retrofits job-intensive; creates local employment (can't be outsourced)
  • Fastest Climate Solution: Efficiency reduces emissions immediately with no new generation needed; fastest deployment timeline
  • Regional Variation: Developing nations more potential (less efficient baseline); developed nations already ~50% of potential realized
  • Deep Decarbonization: Efficiency essential but insufficient; must combine with renewable generation + electrification + behavioral change to reach net-zero
  • Investment Required: ~$300-400 billion annually needed for global efficiency improvements; ~0.3-0.4% of global GDP; financially feasible

💡 Exam Tip: Conservation = most cost-effective climate solution; 20-30% energy reduction possible. Buildings have highest potential (30-50%); industrial 20-30%, transportation limited. Simple actions: lower thermostat, shorter showers, LED lighting, phantom load reduction = 5-10% household savings. Rebound effect offsets 10-30% (people use more if efficient), so not 100% savings. Barriers: high capital cost, split incentives (landlord/tenant), information gaps, behavioral inertia. Policy: efficiency standards, rebates, financing, education help. Know that efficiency is "first fuel" - cheapest energy to reduce.

🎯 Complete Unit 6 Study Summary - All 13 Topics

✓ Critical Concepts

  • Renewable = replenishable; nonrenewable = finite
  • 80% global energy still from fossil fuels
  • Capacity factor: nuclear 90%, hydro 60-90%, solar 15-25%, wind 35-45%
  • LCOE: solar/wind now cheapest in most regions
  • Energy payback: solar 1-4 years (EROI 6-25)
  • Intermittency main renewable challenge
  • Nuclear zero-carbon but waste/cost issues
  • Conservation = most cost-effective solution

⚠️ Don't Confuse These

  • Efficiency % vs. capacity factor
  • Power vs. energy (kW vs. kWh)
  • Fossil fuels declining (false - still growing!)
  • All hydro "clean" (ecosystem impacts real)
  • All biomass renewable (deforestation issues)
  • Hydrogen ready now (still experimental)
  • Solar/wind need no backup (intermittency!)
  • Efficiency = full energy reduction (rebound effect!)

📚 AP Exam Success Strategy for Unit 6

Know the energy ladder: Conservation (first priority) → Efficiency → Renewables → Nuclear → Fossil Fuels (last resort). Understand tradeoffs: Every energy source has advantages AND disadvantages; no perfect solution. Be quantitative: Know percentages (global mix, capacity factors), calculate power/energy, understand EROI and carbon intensity. Think systems: How does each source fit grid? What backup needed? Storage requirements? Environmental justice: Who bears costs/benefits? Impacts unequally distributed. Know timelines: Which solutions ready now (solar, wind, efficiency) vs. future (hydrogen, fusion, advanced geothermal). Practice calculations: Power = ½ρAv³, head-flow relationship for hydro, energy payback calculations.

🔑 Final Key Points

  • Baseload power: Nuclear, hydro (with storage), geothermal, coal. Needed for grid stability.
  • Variable renewables: Solar, wind. Need storage, smart grid, geographic diversity to manage intermittency.
  • Storage technologies: Batteries (1-4 hours), pumped hydro (4-24+ hours), thermal storage, hydrogen (long-term, expensive).
  • Global resources: Oil/gas concentrated (Middle East, Russia); coal distributed; renewables widely available (enables independence).
  • Climate imperative: Must transition away from fossil fuels for climate stabilization. Renewables + nuclear + conservation only path to net-zero.
  • Economic reality: Solar/wind now cheapest electricity; transition accelerating; fossil fuel new capacity increasingly uneconomical.
  • Behavioral change essential: Technology alone insufficient; consumption reduction needed alongside efficiency/renewable deployment.
  • Complex tradeoffs: Every choice involves environmental/social/economic costs. Holistic thinking required; no perfect solution.

🎯 Unit 6 Key Takeaways for AP Exam Success

✓ Must-Know Concepts

  • Renewable vs. nonrenewable distinction
  • Global energy mix (80% fossil, 20% renewable)
  • Capacity factor (actual vs. potential output)
  • Efficiency percentages for each source
  • Pros/cons of each energy source
  • Resource distribution globally
  • Emerging technologies (EVs, H₂, SMRs)
  • Conservation potential and barriers

⚠️ Common Mistakes to Avoid

  • Solar/wind 100% efficient (not - ~20-40%)
  • Renewables unlimited capacity (varying factors)
  • Nuclear = always bad (low-carbon crucial)
  • Hydrogen ready to replace gas (still experimental)
  • Hydro has no environmental impacts
  • All biofuels sustainable (food competition!)
  • Fossil fuels being phased out (still growing)
  • Conservation solves everything alone

📚 Study Strategies for Unit 6

Create comparison charts for all energy sources (efficiency, emissions, cost, scalability, environmental impacts). Know percentages of global electricity generation. Understand capacity factors (actual output ÷ theoretical max). Compare EROI (energy returned on invested). Know which fuels best for transportation/heating/electricity. Understand grid requirements for renewable integration (storage, transmission). Practice calculations: kWh needed, carbon emissions avoided, cost comparisons. Know emerging technologies and barriers to adoption.